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Thursday, December 16, 2010

Sugar and Cornstarch Make Environmentally Safer Plastics

Sugar and corn starch used to make biodegradable plastics

Most plastics are made from petroleum, and that's a problem on two fronts: crude oil is a finite resource, and conventional plastics persist in the environment for centuries. Biodegradable alternatives made from plant materials have been around for a while, but they've historically come with compromises — they tend to be weaker, more expensive, or harder to process than conventional plastics. New research is changing that picture, using everyday agricultural inputs like corn starch and sugar to produce biodegradable plastics that are not only more sustainable but actually tougher than many petrochemical alternatives.

The plastic in question is polylactic acid, or PLA — a biodegradable polymer made from lactic acid, which is derived from fermenting plant sugars (corn, wheat, sugarcane). PLA can already be found in packaging, food containers, and medical devices. Its big appeal is that it breaks down in industrial composting conditions within months, compared to the hundreds of years conventional plastics persist. The challenge has been making it strong and versatile enough to replace plastics in demanding applications.

The Role of Better Catalysts

The key advance in the new research involves the development of improved catalysts for polymerizing lactide — the ring-shaped molecule that serves as the building block for PLA. Better catalysts give manufacturers more control over the polymerization process, allowing them to tune the molecular structure of the resulting plastic. By controlling things like chain length, branching, and crystallinity, they can produce PLA grades with significantly enhanced mechanical properties — tougher, more heat-resistant, or more flexible depending on the application.

Safe, Green, and Practical

Corn-based PLA is also notable from a health perspective. Unlike some petroleum-derived plastics that can leach potentially harmful compounds, PLA is generally considered safe and is already approved for food-contact uses. A plastic that degrades in a backyard compost bin in a matter of months, poses no chemical hazard risks, and can be derived entirely from renewable agricultural feedstocks represents a genuinely compelling option for a world trying to reduce its plastic footprint.

There's still work to do — PLA remains more expensive than conventional plastics at current production scales, and industrial composting infrastructure is not universally available. But the materials science is advancing rapidly, and this kind of research is closing the gap.


Source: Chemistry World

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